Three-dimensional Covalent Organic Frameworks (3D COFs) possess highly tunable porous structures that hold immense potential for advanced device applications. However, their integration into active nano- and microsystems is currently bottlenecked by conventional solvothermal synthesis methods. These traditional approaches require prolonged reaction times (>12 h) and typically yield...
In equilibrium statistical physics, the fluctuation-compressibility theorem states that the variance of the number of particles, in a region of space with size $R$ , scales as $σ_N∼R^d$, with d the spatial dimension. Active systems, however, often exhibit giant number fluctuations (GNF), where $σ_N∼R^d$, with $β>d$. In contrast, when $β
Metal–organic frameworks (MOFs) are porous coordination polymers characterized by high surface areas and broad application potential, particularly in biomedicine. However, their conventional synthesis often relies on dangerous organic solvents such as N,N-dimethylformamide (DMF), N,N-dimethylacetamide (DMA), and N,N-diethylformamide (DEF)[1, 2]. Among these materials, MIL-53 (Fe) was selected...
